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Sure – Just like any other file associate issue.
Browse to C:\Windows\System32
Scroll down to services.msc (or any other .msc for that matter) > Right-Click, Open With... > Click 'Browse', Navigate to – c:\WINDOWS\system32\mmc.exe > Tick 'Always use this program to...' > Press OK.
Otherwise you can do this through the registry instead, though it's a little more involved :)
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posted 2008-Nov-10, 8pm AEST
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